Identification of polymers as major components of atmospheric organic aerosols.
نویسندگان
چکیده
Results from photooxidation of aromatic compounds in a reaction chamber show that a substantial fraction of the organic aerosol mass is composed of polymers. This polymerization results from reactions of carbonyls and their hydrates. After aging for more than 20 hours, about 50% of the particle mass consists of polymers with a molecular mass up to 1000 daltons. This results in a lower volatility of this secondary organic aerosol and a higher aerosol yield than a model using vapor pressures of individual organic species would predict.
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ورودعنوان ژورنال:
- Science
دوره 303 5664 شماره
صفحات -
تاریخ انتشار 2004